Removal of phosphate (PO43-) from aqueous solution using nZVI@OPP: synthesis, characterization, and performance evaluation

Abstract

In recent times, nZVI composites have been developed as environmentally friendly adsorbents to tackle the issue of eutrophication in freshwater bodies. Herein, we synthesized nano zero valent iron loaded orange peel powder (nZVI@OPP) in different proportions (1:1, 1:3, 1:5, and 1:10) and investigated its PO4 3- elimination potential from water. Amongst, nZVI@OPP (1:5) composite presented excellent PO4 3- removal performance (93.32 %) comparable to that of 1:1 (100 %) and 1:3 (98.99 %), and therefore was selected for further analysis. The physicochemical properties of nZVI@OPP (1:5) also showed porous and irregular surface with more available sorption sites and reactive functional groups, than planar and crystal surface of raw OPP, as revealed by SEM-EDX, XRD, FT-IR, and elemental mapping. The optimum conditions (nZVI@OPP (1:5) dosage: 2 g/L, contact time: 60 mins, pH: 7, initial PO4 3- concentration: 10 mg/L, and temp: 298 K) indicated 93.32 % PO4 3- removal from simulated water samples. Based on higher R2 values, PSO kinetic and Langmuir isotherm models showed better fitting with PO4 3- sorption data. Moreover, various coexisting anions posed negative impact on PO4 3- removal in the given order: NO3 - < SO4 2 < Cl- < mixed anions, while no significant impact of thermal variations on PO4 3- removal was observed. The spent nZVI@OPP (1:5) also showed reasonable reusability potential when removing PO4 3- from aqueous solution. The dominant PO4 3- removal mechanisms including physisorption, chemisorption, ligand exchange, and complexation reactions were identified. In general, current study provides new insights into the importance of selecting appropriate mixing proportion of nZVI and OPP, with the potential of extracting maximum PO4 3- content from water considering economic and waste management perspective.